Cr(VI) removal from aqueous solution with bamboo charcoal chemically modified by iron and cobalt with the assistance of microwave
Wei Wang , Xuejiang Wang
,
Xin Wang
,
Lianzhen Yang
,
Zhen Wu
,
Siqing Xia
,
Jianfu Zhao
DOI:10.1016/S1001-0742(12)60247-2
Received November 13, 2012,Revised April 12, 2013, Accepted , Available online September 06, 2013
Volume ,2013,Pages 1726-1735
Bamboo charcoal (BC) was used as starting material to prepare Co-Fe binary oxideloaded adsorbent (Co-Fe-MBC) through its impregnation in Co(NO3)2, FeCl3 and HNO3 solutions simultaneously, followed by microwave heating. The low-cost composite was characterized and used as an adsorbent for Cr(VI) removal from water. The results showed that a cobalt and iron binary oxide (CoFe2O4) was uniformly formed on the BC through redox reactions. The composite exhibited higher surface area (331 m2/g) than that of BC or BC loaded with Fe alone (Fe-MBC). The adsorption of Cr(VI) strongly depended on solution pH, temperature and ionic strength. The adsorption isotherms followed the Langmuir isotherm model well, and the maximum adsorption capacities for Cr(VI) at 288 K and pH 5.0 were 35.7 and 51.7 mg/g for Fe-MBC and Co-Fe-MBC, respectively. The adsorption processes were well fitted by the pseudo second-order kinetic model. Thermodynamic parameters showed that the adsorption of Cr(VI) onto both adsorbents was feasible, spontaneous, and exothermic under the studied conditions. The spent Co-Fe-MBC could be readily regenerated for reuse.
