Preparation and characterization of PVDF-glass fiber composite membrane reinforced by interfacial UV-grafting copolymerization
Nan Luo
,
Rongle Xu
,
Min Yang
,
Xing Yuan
,
Hui Zhong
,
Yaobo Fan
DOI:10.1016/j.jes.2015.04.027
Received January 15, 2015,Revised March 24, 2015, Accepted April 02, 2015, Available online August 19, 2015
Volume 38,2015,Pages 24-35
A novel inorganic–organic composite membrane, namely poly(vinylidene fluoride) PVDF-glass fiber (PGF) composite membrane, was prepared and reinforced by interfacial ultraviolet (UV)-grafting copolymerization to improve the interfacial bonding strength between the membrane layer and the glass fiber. The interfacial polymerization between inorganic–organic interfaces is a chemical cross-linking reaction that depends on the functionalized glass fiber with silane coupling (KH570) as the initiator and the polymer solution with acrylamide monomer (AM) as the grafting block. The Fourier transform infrared spectrometer-attenuated total reflectance (FTIR-ATR) spectra and the energy dispersive X-ray (EDX) pictures of the interface between the glass fiber and polymer matrix confirmed that the AM was grafted to the surface of the glass fiber fabric and that the grafting polymer was successfully embedded in the membrane matrix. The formation mechanisms, permeation, and anti-fouling performance of the PGF composite membrane were measured with different amounts of AM in the doping solutions. The results showed that the grafting composite membrane improved the interfacial bonding strength and permeability, and the peeling strength was improved by 32.6% for PGF composite membranes with an AM concentration at 2 wt.%.
