Ultrasensitive and selective 4-aminophenol chemical sensor development based on nickel oxide nanoparticles decorated carbon nanotube nanocomposites for green environment


Mohammad Musarraf Hussain , Mohammed M. Rahman , Abdullah M. Asiri

DOI:10.1016/j.jes.2016.03.028

Received January 19, 2016,Revised March 02, 2016, Accepted March 07, 2016, Available online June 16, 2016

Volume 53,2017,Pages 27-38

Nickel oxide nanoparticles decorated carbon nanotube nanocomposites (NiO·CNT NCs) were prepared in a basic medium by using facile wet-chemical routes. The optical, morphological, and structural properties of NiO·CNT NCs were characterized using Fourier transformed infra-red (FT-IR), Ultra-violet visible (UV/Vis) spectroscopy, field-emission scanning electron microscopy (FESEM), X-ray energy dispersed spectroscopy (XEDS), X-ray photoelectron spectroscopy (XPS), and powder X-ray diffraction (XRD) methods. Selective 4-aminophenol (4-AP) chemical sensor was developed by a flat glassy carbon electrode (GCE, surface area: 0.0316 cm2) fabricated with a thin-layer of NCs. Electrochemical responses including higher sensitivity, large dynamic range (LDR), limit of detection (LOD), and long-term stability towards 4-AP were obtained using the fabricated chemical sensors. The calibration curve was found linear (R2 = 0.914) over a wide range of 4-AP concentration (0.1 nmol/L–0.1 mol/L). In perspective of slope (2 × 10− 5 μA/μM), LOD and sensitivity were calculated as 15.0 ± 0.1 pM and ~ 6.33 × 10− 4 μA/(μM·cm) respectively. The synthesized NiO·CNT NCs using a wet-chemical method is a significant route for the development of ultrasensitive and selective phenolic sensor based on nano-materials for environmental toxic substances. It is suggested that a pioneer and selective development of 4-AP sensitive sensor using NiO·CNT NCs by a facile and reliable current vs voltage (I–V) method for the major application of toxic agents in biological, green environmental, and health-care fields in near future.

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