Development of MoS2-stainless steel catalyst by 3D printing for efficient destruction of organics via peroxymonosulfate activation
Peng Liu , Yufeng Liu , Jianhui Xu , Xin Fu , Pengxu Wang , Dan Li , Yunfei Zhang , Shenggui Chen , Chunhui Zhang
DOI:10.1016/j.jes.2023.01.016
Received December 05, 2022,Revised , Accepted January 17, 2023, Available online January 25, 2023
Volume 36,2024,Pages 108-117
Herein, a novel MoS2-stainless steel composite material was first synthetized via a 3D printing method (3DP MoS2-SS) for peroxymonosulfate (PMS) activation and organics degradation. Compared with MoS2-SS powder/PMS system (0.37 g/(m2/min)), 4.3-fold higher kFLO/SBET value was obtained in 3DP MoS2-SS/PMS system (1.60 g/(m2/min), resulting from the superior utilization of active sites. We observed that 3DP MoS2-SS significantly outperformed the 3DP SS due to the enhanced electron transfer rate and increased active sites. Moreover, Mo4+ facilitated the Fe2+/Fe3+ cycle, resulting in the rapid degradation of florfenicol (FLO). Quenching experiments and electron paramagnetic resonance spectra indicated that •OH, SO4•−, O2•− and 1O2 were involved in the degradation of FLO. The effect of influencing factors on the degradation of FLO were evaluated, and the optimized degradation efficiency of 98.69% was achieved at 1 mM PMS and pH of 3.0. Six degradation products were detected by UPLC/MS analyses and several possible degradation pathways were proposed to be the cleavage of C-N bonds, dechlorination, hydrolysis, defluorination and hydroxylation. In addition, 3DP MoS2-SS/PMS system also demonstrated superior degradation performance for 2-chlorophenol, acetaminophen, ibuprofen and carbamazepine. This study provided deep insights into the MoS2-SS catalyst prepared by 3DP technology for PMS activation and FLO-polluted water treatment.
